Spectrophotometric Determination of Cobalt(II) with Eriochrome Black T after Extraction as Methyltrioctylammonium Tetrathiocyanatocobaltate(II)

Extraction of Traces of Copper as Tetra-Butylammonium Tetrathiocyanato Copper (II) and Its Spectrophotometric Determination Using Eriochrome Black T

An extraction-spectrophotometric method for the determination of traces of copper (II) is described. The method is based on the quantitative extraction of copper as tetrabutylammonium tetrathiocyanato copper (II) into methyl isobutyl ketone, followed by spectrophotometric determination, using eriochrome black T as a metallochromic indicator. The red-violet mixed complex of copper absorbs at...

Electrocatalytic Determination of Isoniazid by a Glassy Carbon Electrode Modified with Poly (Eriochrome Black T)

In this work poly eriochrome black T (EBT) was electrochemically synthesized on the glassy carbon electrode as electrode modifier. On the modified electrode, voltammetric behavior of isoniazid (INH) was investigated. The poly (EBT)-modified glassy carbon electrode has excellent electrocatalytic ability for the electrooxidation of isoniazid. This fact was appeared as a reduced overpotential of I...

Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide

A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 <em...

electrocatalytic determination of isoniazid by a glassy carbon electrode modified with poly (eriochrome black t)

in this work poly eriochrome black t (ebt) was electrochemically synthesized on the glassy carbon electrode as electrode modifier. on the modified electrode, voltammetric behavior of isoniazid (inh) was investigated. the poly (ebt)-modified glassy carbon electrode has excellent electrocatalytic ability for the electrooxidation of isoniazid. this fact was appeared as a reduced overpotential of i...

Selective extraction spectrophotometric determination